IMINE PHOTOALKYLATIONS . PAPAVERINE PHENANTHRIDINE AND A GENERAL MECHANISM

被引：55

作者：

STERMITZ, FR

SEIBER, RP

NICODEM, DE

机构：

[1] Departments of Chemistry, Colorado State University, Fort Collins, Colorado

[2] Utah State University, Logan, Utah

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 03期

关键词：

D O I：

10.1021/jo01267a046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Irradiation of papaverine (or its hydrochloride) in methanol and ethanol produced 1-methyl-6,7-dimethoxyisoquinoline and 1-ethyl-6,7-dimethoxyisoquinoline, respectively. Irradiation of phenanthridine in ethanol yielded 6-ethylphenanthridine. A mechanism is described which serves to correlate the present results with a number of alcohol incorporations in imine photochemistry. © 1968, American Chemical Society. All rights reserved.

引用

页码：1136 / &

共 22 条

[1] Hoffman's partial break down of emetin, as well as its dehydrogenation in to emetamine(1)) [J].