KINETICS OF AUTOXIDATION OF ISOTACTIC POLYBUTENE-1 BY INFRARED SPECTROSCOPY

被引：14

作者：

STIVALA, SS

YO, G

REICH, L

机构：

[1] Department of Chemistry and Chemical Engineering, Stevens Institute of Technology, Hoboken, New Jersey

[2] Polymer Research Branch, Picatinny Arsenal, Dover, New Jersey

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1969年 / 13卷 / 06期

关键词：

D O I：

10.1002/app.1969.070130616

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The autoxidation of a film of isotactic polybutene‐1 (IPB) containing a relatively large amount of metallic ash (≈0.2%) was studied by means of infrared spectroscopy. Reaction temperatures were varied from 105 to 120°C and oxygen concentrations from 25 to 100% by volume. A reaction scheme previously reported for the autoxidation of atactic polybutene‐1 (APB) was utilized for the IPB. Various results obtained for IPB were compared with those previously reported for APB. Copyright © 1969 John Wiley & Sons, Inc.

引用

页码：1289 / &

共 11 条

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[10] KINETICS OF UNCATALYZED THERMAL OXIDATION OF ATACTIC POLYBUTENE-1 BY INFRARED SPECTROSCOPY [J].

STIVALA, SS ;

KAPLAN, EB .

JOURNAL OF APPLIED POLYMER SCIENCE, 1965, 9 (11) :3557-&

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