INSERTION OF ACETYLENES INTO THE SI-PT BOND AFFORDING (BETA-SILYLVINYL)PLATINUM COMPLEXES

被引：42

作者：

YAMASHITA, H ^{[1
]}

TANAKA, M ^{[1
]}

GOTO, M ^{[1
]}

机构：

[1] NATL CHEM LAB IND,TSUKUBA,IBARAKI 305,JAPAN

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 04期

关键词：

D O I：

10.1021/om00028a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Acetylenes RC=CR (R = Ph, Pr) inserted into the Si-Pt bond of trans-Me3SiPtX(PEt3)2 (X = Br, I) to give trans-(E)-Me3Si(R)C=C(R)PtX(PEt3)2 and its stereoisomers. The structure of trans-(E)-Me3Si(Ph)C=C-(Ph)PtBr(PEt3)2 was determined by X-ray crystallography. The reactivity of trans-Me3SiPtBr(PEt3)2 toward PhC=CPh was remarkably higher than that of trans-HPtBr(PEt3)2.

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页码：988 / 990

页数：3

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