ANOMALOUS DIFFUSION IN THE NEMATIC PHASE OF THIN DISKS

被引:14
作者
ALAVI, A
FRENKEL, D
机构
[1] From Instituut voor Atoom en Molecuulfysica, 1098 SJ Amsterdam
来源
PHYSICAL REVIEW A | 1992年 / 45卷 / 08期
关键词
D O I
10.1103/PhysRevA.45.R5355
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We report molecular-dynamics simulations of the anisotropic diffusion of infinitely thin platelets in the nematic phase. Our simulations are used to distinguish between the predictions of two different theories. The first theory, based on a mapping of the nematic phase of ellipsoidal particles on the hard-sphere fluid, predicts that both the longitudinal and transverse diffusion constants decrease monotonically with increasing density. This is in stark contrast to a scaling argument which suggests that the transverse diffusion constant of platelets in the nematic phase in fact diverges with increasing density. Our simulations support the scaling argument.
引用
收藏
页码:R5355 / R5357
页数:3
相关论文
共 9 条
[1]   DIFFUSION-COEFFICIENT INCREASES WITH DENSITY IN HARD ELLIPSOID LIQUID-CRYSTALS [J].
ALLEN, MP .
PHYSICAL REVIEW LETTERS, 1990, 65 (23) :2881-2884
[2]   MOLECULAR-DYNAMICS SIMULATION USING HARD PARTICLES [J].
ALLEN, MP ;
FRENKEL, D ;
TALBOT, J .
COMPUTER PHYSICS REPORTS, 1989, 9 (06) :301-353
[3]   NONEQUILIBRIUM MOLECULAR-DYNAMICS STUDIES ON THE ANISOTROPIC VISCOSITY OF PERFECTLY ALIGNED NEMATIC LIQUID-CRYSTALS [J].
BAALSS, D ;
HESS, S .
PHYSICAL REVIEW LETTERS, 1986, 57 (01) :86-89
[4]  
Doi M., 1986, THEORY POLYM DYNAMIC
[5]   MONTE-CARLO STUDY OF THE ISOTROPIC AND NEMATIC PHASES OF INFINITELY THIN HARD PLATELETS [J].
EPPENGA, R ;
FRENKEL, D .
MOLECULAR PHYSICS, 1984, 52 (06) :1303-1334
[6]   MOLECULAR-DYNAMICS STUDY OF THE DYNAMICAL PROPERTIES OF AN ASSEMBLY OF INFINITELY THIN HARD-RODS [J].
FRENKEL, D ;
MAGUIRE, JF .
MOLECULAR PHYSICS, 1983, 49 (03) :503-541
[7]   ON THE ANISOTROPY OF DIFFUSION IN NEMATIC LIQUID-CRYSTALS - TEST OF A MODIFIED AFFINE TRANSFORMATION MODEL VIA MOLECULAR-DYNAMICS [J].
HESS, S ;
FRENKEL, D ;
ALLEN, MP .
MOLECULAR PHYSICS, 1991, 74 (04) :765-774
[8]   MOLECULAR-DYNAMICS SIMULATION OF A FLUID OF HARD SPHEROCYLINDERS [J].
REBERTUS, DW ;
SANDO, KM .
JOURNAL OF CHEMICAL PHYSICS, 1977, 67 (06) :2585-2590
[9]  
ZANNONI C, 1979, MOL PHYSICS LIQUID C