OXY FUNCTIONALIZATION OF METAL-COORDINATED HETEROCYCLIC CARBENES

被引：41

作者：

HERRMANN, WA

ROESKY, PW

ELISON, M

ARTUS, G

OFELE, K

机构：

[1] Anorganisch-chemisches Institut der Technischen Universität München, D-85747 Garching bei München

[2] Verband der Chemischen Industrie, Frank furt am Main

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 03期

关键词：

D O I：

10.1021/om00003a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-coordinated 1,3-dimethylimidazolin-2-ylidene ligands undergo osmylation by means of osmium tetraoxide to yield a new type of bimetallic, redox-stable complexes es with metals in, very different oxidation states (e.g. Cr-0/Os-VI). This oxy functionalization does not influence the metal-carbene bond in a significant way (IR and NMR spectra, single-crystal X-ray diffraction structure).

引用

页码：1085 / 1086

页数：2

共 23 条

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