The Crystal Structure and Magnetic Susceptibility of Caesium Argentous Auric Chloride, Cs2AgAuCl6, and Caesium Aurous Auric Chloride, Cs2AuAuCl6

被引：17

作者：

Elliott, Norman ^{[1
]}

机构：

[1] CALTECH, Gates Chem Lab, Pasadena, CA USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1934年 / 2卷 / 07期

关键词：

D O I：

10.1063/1.1749500

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The triple salts Cs2AgAuCl6 and Cs2AuAuCl6 have been investigated by means of magnetic susceptibility measurements and x-ray powder photographs in order to obtain information regarding the general nature of these compounds. Both compounds were found to be diamagnetic. X-ray powder-photographic data lead to a cubic structural unit with a(0) = 5.33A for both crystals. The observed intensity values are in general agreement with the perovskite structure. Small discrepancies, however, suggest that the atomic arrangement varies slightly from the ideal perovskite structure. The detailed nature of the distortion was not determined. The bearing of these results on the valence type of the substances is discussed.

引用

页数：3