SYNTHETIC APPLICATION OF TITANABICYCLES GENERATED FROM 1,6-DIENES OR 1,7-DIENES, ENYNES, AND DIYNES AND (ETA(2)-PROPENE)TI(O-I-PR)(2)

被引：81

作者：

URABE, H ^{[1
]}

HATA, T ^{[1
]}

SATO, F ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT BIOMOLEC ENGN,MIDORI KU,YOKOHAMA,KANAGAWA 226,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 24期

关键词：

D O I：

10.1016/0040-4039(95)00727-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title unsaturated compounds and a stoichiometric amount of (eta(2)-propene)Ti(O-i-Pr)(2) afforded titanabicycles, which, upon hydrolysis, gave substituted cyclopentane and cyclohexane frameworks. The titanacycles could be also intercepted with deuterium, iodine, or carbon monoxide.

引用

页码：4261 / 4264

页数：4

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