PLANAR COMPLEXES CONTAINING METAL-METAL BONDS

被引：423

作者：

KROGMANN, K

机构：

[1] Laboratorium für Anorganische Chemie Universität, Stuttgart

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1969年 / 8卷 / 01期

关键词：

Coordination modes; Metal–metal interactions; Platinum;

D O I：

10.1002/anie.196900351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Planar complexes, and particularly those of platinum, can form structures containing linear chains of heavy metal atoms with metal‐metal distances as short as 3.1 Å. The bonding in these chains can be strengthened by partial oxidation, and the bond lengths can be reduced to 2.8 Å in this way. Model structures for the novel nonstoichiometric products, such as K2[Pt(CN)4]Cl0·32 · 2.6 H2O, are considered. The bonding is also discussed on the basis of a one‐dimensional band model. Copyright © 1969 by Verlag Chemie, GmbH, Germany

引用

页码：35 / &

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