PYROLYSIS OF THIO- AND ISOTHIO-CYANATES .I. SOME SIMPLE ALKYL ISOTHIOCYANATES

被引：9

作者：

BARROETA, N

MACCOLL, A

机构：

[1] William Ramsay and Ralph Forster Laboratories, University College

[2] Instituto di Chimica Generale, Universita di Pisa, Pisa, Via Risorgimento

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 04期

关键词：

D O I：

10.1039/j29690000347

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The gas-phase decomposition of ethyl, isopropyl, and t-butyl isothiocyanates has been studied in the pressure range of 35-350 mm. The reaction, which has been found to be the unimolecular elimination of thiocyanic acid, is followed by a slow addition of the acid to the olefins to yield mainly the isothiocyanate expected by Markownikoff addition.

引用

页码：347 / &

共 5 条

[1]

BARROETA N, 1968, THESIS U LONDON

[2] ISONITRILE-NITRILE ISOMERIZATION [J].