PROTON EXCHANGE AND HYDROGEN BONDING IN HYDROXYLAMINE DERIVATIVES

被引：7

作者：

FEUER, H

PEELE, D

BRAUNSTEIN, DM

RAO, CNR

机构：

[1] Department of Chemistry, Purdue University, Lafayette

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 08期

关键词：

D O I：

10.1016/0584-8539(69)80122-4

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Proton exchange in hydroxylamines, RNHOH, has been investigated by nuclear magnetic resonance spectroscopy. Hydrogen bonding of the hydroxylamines and their N,N-and N,O-disubstituted derivatives by self-association as well as by their interaction with electron donors has been studied by nuclear magnetic resonance and infrared spectroscopy. The results indicate that the OH group participates to a greater extent in hydrogen bonding than the NH group. The O-H⋯Y (Y = donor site) hydrogen bonds are found to be generally stronger than the N-H⋯Y bonds. © 1969.

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页码：1393 / +

页数：1

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