SYNTHESIS AND MOLECULAR AND CRYSTAL-STRUCTURES OF (3-METHYL-3-BENZOBOREPIN)CHROMIUM TRICARBONYL

被引：34

作者：

ASHE, AJ

KAMPF, JW

KAUSCH, CM

KONISHI, H

KRISTEN, MO

KROKER, J

机构：

[1] Department of Chemistry, The University of Michigan, Ann Arbor

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 11期

关键词：

D O I：

10.1021/om00161a025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(3-Methyl-3-benzoborepin)chromium tricarbonyl was obtained by treating the free ligand with tris-(acetonitrile)chromium tricarbonyl in refluxing tetrahydrofuran. Red crystals of the complex C14H11BCrO3 form in the P21/n space group with Z = 4, a = 9.421 (2) Å, b = 14.046 (3) Å, c = 9.949 (2) Å, and β = 98.63 (1)°. The full structure has been determined and indicates that chromium is η7-coordinated to the borepin rather than the benzo ring. © 1990, American Chemical Society. All rights reserved.

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页码：2944 / 2948

页数：5

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