Motional effects in the Mossbauer spectra of iron(II) hexammines

被引：15

作者：

Asch, L. ^{[1
]}

Adloff, J. P. ^{[1
]}

Friedt, J. M. ^{[1
,2
]}

Danon, J. ^{[2
]}

机构：

[1] Univ Strasbourg 1, CNRS, Chim Nucl Lab, F-67 Strasbourg 3, France

[2] Ctr Brasileiro Pesquisas Fis, Rio De Janeiro, Brazil

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 5卷 / 02期

关键词：

D O I：

10.1016/0009-2614(70)80014-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Mossbauer spectra of Fe(NH3)(6)Cl-2 change from one single line to a quadrupole doublet with decreasing temperature. The reversed transition is observed on reheating. but at a different temperature. The explanation is based on the temperature-dependent rotation frequency of the ligands.

引用

页码：105 / 108

页数：4

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