TOWARDS CONFORMATIONALLY DEPENDENT REDOX-RESPONSIVE MOLECULAR SWITCHES - NEW POLYFERROCENE BIS BENZO CROWN-ETHER RECEPTORS

被引：25

作者：

BEER, PD

CRANE, CG

DANKS, JP

GALE, PA

MCALEER, JF

机构：

[1] UNIV BIRMINGHAM,DEPT CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

[2] MEDISENSES UK,ABINGDON OX14 1RL,OXON,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 490卷 / 1-2期

关键词：

IRON; POLYFERROCENE; CROWN ETHERS; MOLECULAR SWITCHES; REDOX COUPLES; POTASSIUM COMPLEXES;

D O I：

10.1016/0022-328X(94)05191-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New polyferrocene bis benzo-15-crown-5 ligands have been prepared and shown to form 1:1 intramolecular sandwich complexes with the potassium cation. Electrochemical investigations reveal that both receptors undergo small anodic perturbations of the respective ferrocene-ferrocenium redox couples in the presence of alkali metal cations.

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页码：143 / 148

页数：6

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