THE EFFECT OF ORGANIC AND INORGANIC CHLORIDES ON THE FORMATION OF HCL WITH VARIOUS HYDROGEN-CONTAINING SOURCES IN A FLUIDIZED-BED INCINERATOR

被引：16

作者：

WEY, MY

FANG, TJ

机构：

[1] Dept. of Environmental Engineering, Chung-Hsing University, Taichung

来源：

ENVIRONMENT INTERNATIONAL | 1995年 / 21卷 / 04期

关键词：

D O I：

10.1016/0160-4120(95)00036-K

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

A laboratory scale fluidized bed incinerator was used to examine the hydrogen chloride formation resulting from the presence of organic and inorganic chlorides. Polyvinyl chloride, PVC) and NaCl were used as organic and inorganic chlorides respectively. In order to check the level of HCl generated, additives (sawdust and water) were used to offer the Hydrogen containing source needed for HCl formation. Various operating conditions (temperature in sand bed and freeboard) ware also studied to characterize the potential of HCl emission. The amount of HCl generated from NaCl and PVC was found to be quite different under various operating conditions and additives.

引用

页码：423 / 431

页数：9

共 19 条

[1]

Abbas, Sorvik, On the thermal degradation of poly(vinyl chloride), Structural changes during degradation in nitrogen, 19, pp. 2991-3006, (1973)

[2]

Abbas, Sorvic, On the thermal degradation of poly(vinyl chloride), An apparatus for investigation of early stage of thermal degradation, 17, pp. 3567-3576, (1973)

[3]

Abbas, Sorvik, On the thermal degradation of poly(vinyl chloride), The effect of atmosphere, 17, pp. 3577-3594, (1973)

[4]

Abbas, Sorvic, On the thermal degradation of poly(vinyl chloride), Initiation sites of dehydrochlorination, 20, pp. 2395-2406, (1973)

[5]

Boettner, Ball, Weiss, Analysis of the volatile combustion products of vinyl plastics, Journal of Applied Polymer Science, 13, pp. 377-391, (1969)

[6]

Carroll, Hirschler, Smith, Kinetic modeling of generation and decay of HCl from burning PVC, J. Vinyl Technol., 10, 3, pp. 106-110, (1988)

[7]

Clesceri, Greenberg, Trussel, Standard methods for the examination of water and wastewater, (1987)

[8]

Crosato-Amaldi, Palma, Peggion, Talamini, Investigations on the dehydrochlorination of poly (vinyl-chloride), J. Polym. Sci., 8, pp. 747-754, (1964)

[9]

Evlanov, Formation of free chlorine during combustion of chlorocarbon substance, Fizika Goreniya i Vzryva, 29, pp. 14-16, (1993)

[10]

Galloway, Hirschler, Smith, Model for the generation of hydrogen chloride from the combustion of poly(vinyl chloride) under conditions of forcefully minimized decay, Eur. Polym. J., 25, pp. 149-158, (1989)

← 1 2 →