TANDEM TRANSANNULAR RADICAL CYCLIZATIONS - TOTAL SYNTHESES OF (+/-)-MODHEPHENE AND (+/-)-EPI-MODHEPHENE

被引：44

作者：

CURRAN, DP

WANG, S

机构：

[1] Department of Chemistry, University of Pittsburgh, Pittsburgh

来源：

TETRAHEDRON | 1993年 / 49卷 / 04期

关键词：

D O I：

10.1016/S0040-4020(01)80321-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Modhephene and epi-modhephene have been synthesized by a new tandem transannular radical cyclization strategy. The key tandem cyclization is conducted by the Barton thiohydroxamate method with an exo(methylene)cyclooctane.

引用

页码：755 / 770

页数：16

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