NUCLEOPHILIC TRIFLUOROMETHYLATION OF ORGANIC SUBSTRATES USING (TRIFLUOROMETHYL)TRIMETHYLSILANE IN THE PRESENCE OF A FLUORIDE ANION - .2. A CONVENIENT ROUTE TO ARYLTRIFLUOROMETHYL-SULFIDES, ARYLTRIFLUOROMETHYL-SULFOXIDES AND ARYLTRIFLUOROMETHYL-SULFONES

被引：54

作者：

MOVCHUN, VN ^{[1
]}

KOLOMEITSEV, AA ^{[1
]}

YAGUPOLSKII, YL ^{[1
]}

机构：

[1] UKRAINIAN ACAD SCI, INST ORGAN CHEM, KIEV 253660, UKRAINE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 70卷 / 02期

关键词：

NUCLEOPHILIC TRIFLUOROMETHYLATION; (TRIFLUOROMETHYL)TRIMETHYLSILANE; FLUORIDE ANION; ARYLTRIFLUOROMETHYLSULFIDES; ARYLTRIFLUOROMETHYLSULFOXIDES; ARYLTRIFLUOROMETHYLSULFONES;

D O I：

10.1016/0022-1139(94)03124-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aryltrifluoromethyl-sulfides, -sulfoxides and -sulfones can be prepared by trifluoromethylation of the corresponding arylsulfenyl, -sulfinyl and -sulfonyl halides using (trifluoromethyl)trimethylsilane in the presence of fluoride sources, such as TASF [tris(dimethylamino)sulfonium difluorotrimethylsilicate].

引用

页码：255 / 257

页数：3

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[4]

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[8]

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[9]

YAGUPOLSKII LM, 1975, SYNTHESIS-STUTTGART, P721

[10]

YAGUPOLSKII LM, 1965, ZH OBSHCH KHIM, V35, P377

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