ASSIGNMENT OF RELATIVE AND ABSOLUTE-CONFIGURATION OF ACYCLIC POLYOLS AND AMINOPOLYOLS BY CIRCULAR-DICHROISM - TRENDS FOLLOW FISCHER SUGAR FAMILY TREE

被引：21

作者：

ZHOU, P ^{[1
]}

BEROVA, N ^{[1
]}

WIESLER, WT ^{[1
]}

NAKANISHI, K ^{[1
]}

机构：

[1] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027

来源：

TETRAHEDRON | 1993年 / 49卷 / 41期

关键词：

1,2-POLYOLS; 1-AMINOPOLYOLS; ABSOLUTE CONFIGURATION; CD; EXCITON CHIRALITY METHOD;

D O I：

10.1016/0040-4020(93)80020-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reference CD curves (measured in methylcyclohexane) of a homologous series of 1,2-polyols up to pentols derivatized as anthroates at 1-OH and p-methoxycinnamates at the remaining hydroxyl groups show a systematic trend that greatly simplifies assignments of relative and absolute configurations. The same trend also holds for the corresponding 1-aminopolyols, but not for 2-aminopolyols.

引用

页码：9343 / 9352

页数：10

共 17 条

[1] BACTERIAL STEROL SURROGATES - DETERMINATION OF THE ABSOLUTE-CONFIGURATION OF BACTERIOHOPANETETROL SIDE-CHAIN BY HEMISYNTHESIS OF ITS DIASTEREOISOMERS [J].