INTRAMOLECULAR ALKYLATION AS AN APPROACH TO CYCLIC SULFONES AND SULFIDES

被引：45

作者：

TRUCE, WE

HOLLISTE.KR

LINDY, LB

PARR, JE

机构：

[1] Department of Chemistry, Purdue University, Lafayette

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 01期

关键词：

D O I：

10.1021/jo01265a009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of cyclobutyl, cyclopentyl, and substituted pentamethylene sulfones have been prepared by α,ω-dehydrohalogenation of the corresponding ω-chloroalkyl sulfones. Several aryl cyclopropyl sulfides and 2-phenyltetrahydrothiophenes have also been prepared in this manner from the ω-chloroalkyl sulfides. This approach represents a useful synthesis of these and similar types of compounds. © 1968, American Chemical Society. All rights reserved.

引用

页码：43 / &

共 25 条

[1]

ARCHER S, 1952, Patent No. 668562

[2]

ARCHER S, 1952, Patent No. 2618640

[3]

ARCHER S, 1953, CA 5447, V47

[4] A comparison of the rates of formation of six- and seven membered ring compounds from omega-chloro-sulphides [J].