OBSERVATION OF OH(V=0,1) IN REACTIONS OF O(3P) WITH HCL (V=0,1,2)

被引：37

作者：

BUTLER, JE

HUDGENS, JW

LIN, MC

SMITH, GK

机构：

[1] Laser Chemistry Group, Chemistry Division, Naval Research Laboratory, Washington

来源：

CHEMICAL PHYSICS LETTERS | 1978年 / 58卷 / 02期

关键词：

D O I：

10.1016/0009-2614(78)80280-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The analysis of the observed OH (υ = 0, 1) concentration in the laser enhanced reactions of HCl (υ = 1, 2) with O(3P) atoms demonstrates that vibrational energy in excess of the thermal activation energy barrier continues to enhance the reaction rate. This reaction also exhibits a preferential conversion of reactant vibrational excitation into product vibrational excitation. © 1978.

引用

页码：216 / 220

页数：5

共 19 条

[1] REACTION OF VIBRATIONALLY EXCITED HCL WITH OXYGEN AND HYDROGEN-ATOMS
ARNOLDI, D
WOLFRUM, J
[J]. CHEMICAL PHYSICS LETTERS, 1974, 24 (02) : 234 - 238
[2] EFFECT OF CHANGING REAGENT ENERGY ON REACTION DYNAMICS .8. HIGHLY VIBRATIONALLY-EXCITED PRODUCT FROM THERMONEUTRAL REACTION CL+OH(UPSILON =] 9) -] HCL(UPSILON =] 11) + O
BLACKWELL, BA
POLANYI, JC
SLOAN, JJ
[J]. CHEMICAL PHYSICS, 1977, 24 (01) : 25 - 35
[3] RELAXATION OF HCL(UPSILON=1) AND DCL(UPSILON=1) BY O ATOMS BETWEEN 196 AND 400K
BROWN, RDH
GLASS, GP
SMITH, WM
[J]. CHEMICAL PHYSICS LETTERS, 1975, 32 (03) : 517 - 520
[4] ABSOLUTE RATE CONSTANTS FOR REACTIONS O(P-3) ATOMS WITH HCL AND HBR
BROWN, RDH
SMITH, IWM
[J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1975, 7 (02) : 301 - 315
[5] BROWN RDH, 1978, J CHEM KINETICS, V10, P1
[6] VIBRATION-VIBRATION ENERGY-TRANSFER IN GASEOUS HCL
BURAK, I
NOTER, Y
RONN, AM
SZOKE, A
[J]. CHEMICAL PHYSICS LETTERS, 1972, 17 (03) : 345 - 346
[7] TEA CHEMICAL LASERS FROM H2 + CL2 AND H2 + BR2
BURAK, I
RONN, AM
SZOKE, A
NOTER, Y
[J]. CHEMICAL PHYSICS LETTERS, 1972, 13 (03) : 322 - &
[8] CLYNE MAA, 1973, PHYSICAL CHEM FAST R
[9] RELATIVE TRANSITION-PROBABILITIES AND ELECTRONIC-TRANSITION MOMENT IN A-X SYSTEM OF OH
CROSLEY, DR
LENGEL, RK
[J]. JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 1975, 15 (7-8) : 579 - 591
[10] Herzberg G., 1950, ELECT SPECTRA ELECT

← 1 2 →