MOLECULAR-STRUCTURE STUDY OF PARTIALLY DEUTERATED SUCCINIC ACID BY H-1 AND H-2 DISTANT ENDOR

被引：14

作者：

BOROSKE, E ^{[1
]}

MAYAS, L ^{[1
]}

MOBIUS, K ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST MOLEK PHYS,D-1000 BERLIN 33,FED REP GER

来源：

JOURNAL OF MAGNETIC RESONANCE | 1979年 / 35卷 / 02期

关键词：

D O I：

10.1016/0022-2364(79)90233-6

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Distant ENDOR was used as a sensitive spectroscopic method for the determination of molecular structure parameters of C2H4(COOD)2 and C2D4(COOH)2 in their diamagnetic singlet ground state. The structural information was obtained by measuring the quadrupole coupling tensors of the deuterium atoms in the CD2 positions and in the intermolecular hydrogen bonds OD ... O and by measuring the dipolar coupling tensors between the protons in the CH2 group and between the carboxylic protons in adjacent hydrogen bonds. The distant ENDOR results agree very well with crystallographic data. © 1979.

引用

页码：231 / 246

页数：16

共 21 条

[1] PROTON SHIELDING TENSORS IN POTASSIUM HYDROGEN MALEATE [J].

ACHLAMA, AM ;

KOHLSCHUTTER, U ;

HAEBERLEN, U .

CHEMICAL PHYSICS, 1975, 7 (02) :287-293

[2] NEUTRON-DIFFRACTION STUDY OF POTASSIUM AND RUBIDIUM HYDROGEN OXYDIACETATE - DYNAMICS OF THEIR HYDROGEN-BONDS [J].

ALBERTSS.J ;

GRENTHE, I .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1973, 29 (DEC15) :2751-2760

[3]

BORGHINI M, 1971, 2ND P INT C POL TARG

[4] H-1, H-2, AND C-13 DISTANT-ENDOR AND DNP STUDIES OF POLARIZATION AND DEPOLARIZATION MECHANISMS IN PARTIALLY DEUTERATED SUCCINIC ACID [J].

BOROSKE, E ;

MOBIUS, K .

JOURNAL OF MAGNETIC RESONANCE, 1977, 28 (03) :325-338

[5]

BOROSKE E, 1976, THESIS BERLIN

[6] 3-DIMENSIONAL REFINEMENT OF THE STRUCTURE OF BETA-SUCCINIC ACID [J].

BROADLEY, JS ;

CRUICKSHANK, DWJ ;

MORRISON, JD ;

ROBERTSON, JM ;

SHEARER, HMM .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1959, 251 (1267) :441-457

[7] OXIDATION AND REDUCTION OF SUCCINIC ACID BY IONIZING-RADIATION [J].

BUDZINSKI, EE ;

BOX, HC .

JOURNAL OF CHEMICAL PHYSICS, 1975, 63 (11) :4927-4929

[8]

DALTON LR, 1972, J AM CHEM SOC, V94, P6930, DOI 10.1021/ja00775a011

[9] ISOTOPIC MIXING IN OO'-DIDEUTEROSUCCINIC ACID SINGLE CRYSTALS [J].

ERICSON, LG ;

CUTTEN, DR .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1969, 6 (02) :273-&

[10]

ERICSON LG, 1969, MOL CRYSTALLOGR LIQU, V6, P351

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