DISPROPORTIONATION REACTIONS OF THE DIMERIC ALLYLIRON COMPOUND [ETA-C3H5FE(CO)3]2 - FORMATION OF NOVEL CATIONIC ETA-3-ALLYLIRONCARBONYL COMPLEXES

被引：3

作者：

GOULIN, CA ^{[1
]}

BAIRD, MC ^{[1
]}

机构：

[1] QUEENS UNIV,DEPT CHEM,KINGSTON K7L 3N6,ONTARIO,CANADA

来源：

INORGANICA CHIMICA ACTA | 1990年 / 168卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)80942-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The metalmetal bonded dimer [(η3-C3H5)Fe (CO)3]2 disproportionates on treatment with a variety of tertiary phosphines, forming the ionic allyl iron complexes [(η3-C3H5)Fe(CO)2L2][(η3- C3H5)Fe(CO)3] (L = PMe3, PEt3, PMe2Ph, PMePh2, PPh3). The iron(0) anionic complex has been reported previously but not the labile, iron(II) cationic complexes, which are better synthesized by treatment of (η3-C3H5)Fe(CO)3Br with the tertiary phosphines. © 1990.

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页码：195 / 199

页数：5

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