DYNAMIC SOLVENT EFFECTS IN ADIABATIC ELECTRON-TRANSFER REACTIONS - ROLE OF TRANSLATIONAL MODES

被引：38

作者：

BAGCHI, B

CHANDRA, A

FLEMING, GR

机构：

[1] UNIV CHICAGO,DEPT CHEM,CHICAGO,IL 60637

[2] UNIV CHICAGO,JAMES FRANCK INST,CHICAGO,IL 60637

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 13期

关键词：

D O I：

10.1021/j100376a001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A molecular theory of the dynamic solvent effects on an outer-sphere adiabatic electron transfer reaction is presented. The theory properly includes the role of the microscopic correlations present in a dense dipolar solvent in the dynamics of an electron-transfer reaction. The theory predicts that the translational modes of the solvent, hitherto neglected in most discussions on electron-transfer reactions, can significantly enhance the rate of an adiabatic electron-transfer reaction. © 1990 American Chemical Society.

引用

页码：5197 / 5200

页数：4

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