ELECTROCHEMISTRY OF THE LIQUID-CRYSTAL N-(P-METHOXYBENZYLIDENE)-P-N-BUTYLANILINE (MBBA) - ROLE OF ELECTRODE-REACTIONS IN DYNAMIC SCATTERING

被引：29

作者：

LOMAX, A

BARD, AJ

HIRASAWA, R

机构：

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1972年 / 119卷 / 12期

关键词：

CHEMICAL REACTIONS - Redox - ELECTROCHEMISTRY - ELECTRODES;

D O I：

10.1149/1.2404069

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemical reduction and oxidation of MBBA were studied by cyclic voltammetry and by controlled potential coulometry. The reduction in DMF leads to the formation of the radical anion which decomposes with a half-life of about 4 sec, apparently by both ec and ece pathways. The oxidation product was unstable on the time scale of this study. The possible importance of electrode reactions in interpreting the dynamic scattering phenomenon in nematic liquid crystals is suggested.

引用

页码：1679 / +

页数：1

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