IONIC PATHWAYS TO 2,3-BENZOFLUORANTHENE

被引：1

作者：

NICOLETTI, I

PEREZ, G

CAPONECCHI, G

POSSAGNO, E

LILLA, E

SPARAPANI, C

机构：

[1] CNR,IST CROMATOG,CP 10,I-00016 MONTEROTONDO,ITALY

[2] CNR,IST CHIM NUCL,I-00016 MONTEROTONDO,ITALY

来源：

CHEMOSPHERE | 1994年 / 28卷 / 10期

关键词：

D O I：

10.1016/0045-6535(94)90021-3

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The protonation of 9-phenylanthracene by decay and radiolytic techniques was carried out in the gaseous phase. The intermediate, a free ion formed with an excess of vibrational energy, underwent fragmentation, intermolecular and intramolecular condensation reactions. The yields of the products are dependent on the protonation exothermicity, whose increase favours the fragmentation process. The self-condensation reaction leads to the formation of 2,3-benzofluoranthene.

引用

页码：1733 / 1739

页数：7

共 16 条

[1] FORMATION OF AROMATIC HYDROCARBONS AT HIGH TEMPERATURES .21. PYROLYSIS OF N-BUTYLBENZENE OVER RANGE OF TEMPERATURES FROM 300 DEGREES TO 90ODEGREES AT 50 DEGREE INTERVALS [J].