A CHEMICAL DICHOTOMY IN QUINOLIZIDINE ALKALOID ACCUMULATION WITHIN THE SECTION SPARTIOIDES OF THE GENUS GENISTA (FABACEAE, GENISTEAE)

被引:8
作者
GREINWALD, R
VANRENSEN, I
VEIT, M
CANTO, P
WITTE, L
机构
[1] UNIV WURZBURG, LEHRSTUHL PHARMAZEUT BIOL, MITTLERER DALLENBERGWEG 64, D-97082 WURZBURG, GERMANY
[2] UNIV COMPLUTENSE, FAC FARM, DEPT BIOL VEGETAL 2, E-28040 MADRID, SPAIN
[3] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG, INST PHARMAZEUT BIOL, D-38106 BRAUNSCHWEIG, GERMANY
关键词
GENISTA; FABACEAE; GENISTEAE; QUINOLIZIDINE ALKALOIDS; CHEMOTAXONOMY;
D O I
10.1016/0305-1978(95)93662-M
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A previous study had revealed unexpected differences in the alkaloid profiles within the Genista cinerea aggregate belonging to the section Spartioides. Extending these analyses the alkaloid patterns of 10 further species of the section Spartioides were investigated. At least 31 alkaloids were detected by GC and GC-MS. A chemical dichotomy was demonstrated for the species of the section Spartioides: one group of species contained the alpha-pyridone alkaloids cytisine, N-methylcytisine and anagyrine as major alkaloids, while the other group contained lupanine, 13-hydroxylupanine and its esters as main compounds. The alkaloidal data do not support the actual concept of the section Spartioides.
引用
收藏
页码:89 / 97
页数:9
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