NMR BEHAVIOR AND CRYSTAL-STRUCTURE OF TRI-TER-BUTYLPHOSPHINEALLYLCHLOROPLATINUM(II)

被引：21

作者：

CARTURAN, G ^{[1
]}

BELLUCO, U ^{[1
]}

DELPRA, A ^{[1
]}

ZANOTTI, G ^{[1
]}

机构：

[1] UNIV PADUA,CTR STUDIO BIOPOLIMERI,I-35100 PADUA,ITALY

来源：

INORGANICA CHIMICA ACTA | 1979年 / 33卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)89469-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The NMR behaviour of the title compound in CDCl3 solution is reported and discussed in terms of the allyl asymmetry induced by the difference in bonding modes between P(t-butyl)3 and Cl-. The X-ray structure determination shows the presence of four possible orientation of the allyl group in the molecule. © 1979.

引用

页码：155 / 160

页数：6

共 42 条

[1] DYNAMIC STEREOCHEMISTRY OF SOME PI-ALLYLPALLADIUM COMPOUNDS
ALEXANDER, CW
JACKSON, WR
SPRATT, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (16) : 4990 - +
[2] [Anonymous], 1974, INT TABLES XRAY CRYS, VIV
[3] TRANS-INFLUENCE - ITS MEASUREMENT AND SIGNIFICANCE
APPLETON, TG
CLARK, HC
MANZER, LE
[J]. COORDINATION CHEMISTRY REVIEWS, 1973, 10 (3-4) : 335 - 422
[4] EVIDENCE FOR RESTRICTED ROTATION OF PT-P BOND OF [NU3-C3H5PT[P(C6H11)3]2]+PF6-
ATTIG, TG
CLARK, HC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 94 (03) : C49 - C52
[5] ALLYL-PLATINUM COMPLEXES - SYNTHESIS FROM BIS(CYCLO-OCTA-1,5-DIENE)PLATINUM AND THEIR DYNAMIC BEHAVIOR IN SOLUTION
BOAG, NM
GREEN, M
SPENCER, JL
GORDON, F
STONE, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 127 (02) : C51 - C54
[6] SYNTHESIS OF NOVEL SIGMA-ALLYL PLATINUM(II) COMPLEXES
CARTURAN, G
SCRIVANTI, A
BELLUCO, U
[J]. INORGANICA CHIMICA ACTA, 1977, 21 (01) : 103 - 108
[7] LIGAND-INDUCED FLUXIONALITY IN SOME ETA3-ALLYLPLATINUM(II) COMPLEXES CONTAINING CHELATING LIGANDS - ISOLATION OF DYNAMIC 1-1 ADDUCTS
CLARK, HC
JABLONSKI, CR
[J]. INORGANIC CHEMISTRY, 1975, 14 (07) : 1518 - 1526
[8] CHEMISTRY OF METAL HYDRIDES .13. INSERTION AND ISOMERIZATION REACTIONS OF ALLYLIC COMPOUNDS WITH CATIONIC PLATINUM(II)-HYDRIDO COMPLEXES
CLARK, HC
KUROSAWA, H
[J]. INORGANIC CHEMISTRY, 1973, 12 (02) : 357 - 362
[9] PI-ALLYL-METAL COMPOUNDS
CLARKE, HL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 80 (02) : 155 - 173
[10] STEREOCHEMICALLY NONRIGID ORGANOMETALLIC COMPOUNDS .4. SOME OBSERVATIONS ON PI-ALLYLIC COMPLEXES
COTTON, FA
FALLER, JW
MUSCO, A
[J]. INORGANIC CHEMISTRY, 1967, 6 (01) : 179 - &

← 1 2 3 4 5 →