THE SYNTHESIS OF SF5-EPOXIDES

被引：9

作者：

WINTER, R

GARD, GL

机构：

[1] Department of Chemistry, Portland State University, Portland

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 50卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)82186-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The epoxidation of two fluorinated pentafluorothio olefins, F5SCHCF2 and F5SCFCF2, was achieved by treatment with NaOCl under phase transfer catalytic conditions at lowered temperatures. Some reactions were run and it was found that in anionic reactions loss of the SF5 group generally occurred. © 1990.

引用

页码：141 / 149

页数：9

共 18 条

[1] PERFLUOROALKYL DERIVATIVES OF SULFUR .17. SOME REACTIONS OF PERFLUOROVINYLSULFUR PENTAFLUORIDE, AND A RE-EXAMINATION OF THERMAL REACTION BETWEEN PERFLUOROPROPENE AND BUTA-1,3-DIENE [J].