LI4[FEN2] - A NITRIDOFERRATE(II) WITH ANIONS ISOSTERIC WITH CO2 - A DEFECT VARIANT OF THE LI3N TYPE-STRUCTURE

被引：34

作者：

GUDAT, A ^{[1
]}

KNIEP, R ^{[1
]}

RABENAU, A ^{[1
]}

机构：

[1] TH DARMSTADT,EDUARD ZINTL INST,W-6100 DARMSTADT,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 02期

关键词：

D O I：

10.1002/anie.199101991

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The continual place-changing of iron atoms in the mixed crystal phases of composition Li4Fe1.04N2, during which the slightly corrigated Li2N layers are maintained, leads in a topotactic reaction to the formation of Li4[FeN2]. This presumably metastable nitridoferrate(II) is one of the lesser known nitridoferrates. Li4[FeN2] crystallizes in a defect variant of the Li3N structure (Li2Fe0.5-square-0.5N), in which Li2N layers are bound by linearly coordinated Fe(II) centers.

引用

页码：199 / 200

页数：2

共 19 条

[1] CORDIER G, IN PRESS Z ANORG ALL
[2] Frankenburger W, 1928, Z ELKTROCHEM ANGEW P, V34, P632
[3] GUDAT A, 1990, Z NATURFORSCH B, V45, P111
[4] LI3FEN2, A TERNARY NITRIDE WITH 1-INFINITY[FEN-4/2(3-)] CHAINS - CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES
GUDAT, A
KNIEP, R
RABENAU, A
BRONGER, W
RUSCHEWITZ, U
[J]. JOURNAL OF THE LESS-COMMON METALS, 1990, 161 (01): : 31 - 36
[5] ON THE CRYSTAL-STRUCTURE OF BANIN, A LOW VALENCY NITRIDONICCOLATE(I)
GUDAT, A
HAAG, S
KNIEP, R
RABENAU, A
[J]. JOURNAL OF THE LESS-COMMON METALS, 1990, 159 (1-2): : L29 - L31
[6] GUDAT A, 1990, THESIS U DUSSELDORF
[7] GUDAT A, IN PRESS Z ANORG ALL
[8] GUDAT A, IN PRESS J LESS COMM
[9] GUDAT A, 1989, 32ND IUPAC C STOCKH, P84
[10] GUDAT A, IN PRESS Z NATURFO B

← 1 2 →