LIGAND-FIELD TRANSITIONS IN M(CO)5L(M=CR,MO,W)

被引：7

作者：

DAAMEN, H ^{[1
]}

OSKAM, A ^{[1
]}

STUFKENS, DJ ^{[1
]}

机构：

[1] UNIV AMSTERDAM,JH VANTHOFF INST,ANORGAN CHEM LAB,AMSTERDAM,NETHERLANDS

来源：

INORGANICA CHIMICA ACTA | 1979年 / 32卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)91668-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The energy diagram of the metal d-orbitals in M(CO)5L complexes is described taking into account both mutual electron repulsion and ligand field effects. The various parameters governing the diagram are estimated from absorption and photoelectron spectra. The LF transitions are assigned in detail and the shifts by replacement of L are discussed. The results show that the lowest excited state has mainly σ*z-character. © 1979.

引用

页码：249 / 252

页数：4

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