PROTONATION OF [(MNIV(SALTN)(MU-2-O))2] RESULTS IN SIGNIFICANT MODIFICATION OF STRUCTURE AND CATALASE-LIKE REACTIVITY

被引：61

作者：

LARSON, EJ ^{[1
]}

RIGGS, PJ ^{[1
]}

PENNERHAHN, JE ^{[1
]}

PECORARO, VL ^{[1
]}

机构：

[1] UNIV MICHIGAN,WILLARD H DOW LABS,DEPT CHEM,ANN ARBOR,MI 48109

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 02期

关键词：

D O I：

10.1039/c39920000102

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Protonation of an {Mn(IV)(mu(2)-O)}2 core to form {(Mn(IV)2(mu(2)-O)(mu(2)-OH)} leads to perturbations of the physical properties of this unit including an increase in metal-metal separation (ca. 0.1 angstrom) and loss of catalase reactivity.

引用

页码：102 / 103

页数：2

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