SYNTHESIS, STRUCTURES, AND REACTIONS OF 2 BIS(DIAMINOSTANNYLENE)S AND A BIS(DIAMINOGERMYLENE) CONTAINING A CENTRAL C-6 RING

被引：61

作者：

BRAUNSCHWEIG, H ^{[1
]}

HITCHCOCK, PB ^{[1
]}

LAPPERT, MF ^{[1
]}

PIERSSENS, LJM ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 11期

关键词：

D O I：

10.1002/anie.199411561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two Sn[N(SiMe3)2] moieties arranged trans, linked by a 1,4‐diaminosubstituted cyclohexane or benzene ring describes the first heteroleptic bis(stannylene)s 1 and 2 (R = SiMe3), respectively; the bis(germylene) is isomorphous with 2. The replacement of the N(SiMe3)2 groups for aryloxy groups takes place on addition of Sn(OAr)2 to 1 and 2; surprisingly, the treatment of 2 with SnCl2 affords the redox products 3 and metallic tin. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1156 / 1158

页数：3

共 12 条

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