[2+1] CARBENOID INSERTION REACTION OF FISCHER CARBENE COMPLEXES WITH SILANES - A SYNTHESIS OF ALLYLSILANES

被引：23

作者：

MAK, CC ^{[1
]}

TSE, MK ^{[1
]}

CHAN, KS ^{[1
]}

机构：

[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,HONG KONG

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 13期

关键词：

D O I：

10.1021/jo00092a016

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Fischer carbene complexes undergo mild insertion reactions with organosilanes to give methoxysilanes in good yields. The effects of catalysts, solvents, and metals have been investigated. The insertion reactions of alkenyl carbene complexes provide a convenient route for the synthesis of allylsilanes.

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页码：3585 / 3589

页数：5

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