AN IN-SITU STM STUDY OF ANION ADSORPTION ON PT(111) FROM SULFURIC-ACID-SOLUTIONS

被引：138

作者：

FUNTIKOV, AM

LINKE, U

STIMMING, U

VOGEL, R

机构：

[1] FORSCHUNGSZENTRUM JULICH, FORSCHUNGSZENTRUM, INST ENERGIEVERFAHRENSTECH, D-52425 JULICH, GERMANY

[2] FORSCHUNGSZENTRUM JULICH, FORSCHUNGSZENTRUM, INST GRENZFLACHENFORSCH & VAKUUMTECH, D-52425 JULICH, GERMANY

[3] RUSSIAN ACAD SCI, AN FRUMKIN ELECTROCHEM INST, MOSCOW 117071, RUSSIA

来源：

SURFACE SCIENCE | 1995年 / 324卷 / 01期

关键词：

ADSORPTION KINETICS; ELECTROCHEMICAL METHODS; LOW INDEX SINGLE CRYSTAL SURFACES; METAL ELECTROLYTE INTERFACES; PLATINUM; SCANNING TUNNELING MICROSCOPY;

D O I：

10.1016/0039-6028(94)00774-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrochemical in-situ STM under clean conditions has been applied to monitor the anion adlattice on Pt(lll) in sulfuric acid solution at atomic scale resolution. The maxima observed in the STM images are arranged in a centered ((21)(12))structure. This structure was found in the potential range between 0.5 V and 0.7 V RHE. The structure is interpreted as a coadsorbate of anions and a solvent species which both form a primitive ((21)(12)) adlattice with a coverage of 20% of a monolayer.

引用

页码：L343 / L348

页数：6

共 16 条

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