RACEMISATION .I. RACEMISATION OF PROTOBERBERINES UNDER CONDITIONS OF CATALYTIC HYDROGENATION

被引：23

作者：

KAMETANI, T

IHARA, M

机构：

[1] Pharmaceutical Institute, School of Medicine, Tohoku University, Sendai, Kitayobancho

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 02期

关键词：

D O I：

10.1039/j39680000191

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of optically active protoberberine alkaloids, namely (-)-coreximine (II), (-)-tetrahydropalmatine (III), and (-)-norcoralydine (IV), with hydrogen in the presence of platinum oxide afforded the corresponding racemic protoberberines. Catalytic hydrogenolysis of (-)-[13,13,13a-D 3]coreximine (VI) and (-)-[13,13,13a-D3]norcoralydine (VIII) gave racemised products with the expected mass spectra.

引用

页码：191 / &

共 10 条

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