EFFECT OF BENDING VIBRATIONS ON THE HIGH OVERTONE SPECTRUM OF THE C-H-BOND MODE IN C6D5H

被引：43

作者：

SAGE, ML

机构：

[1] Department of Chemistry, Syracuse University, Syracuse

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 11期

关键词：

D O I：

10.1021/j100474a019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We investigate the effects of bending vibrations on the high overtone spectrum of the C-H bond mode in C6D5H using a Morse oscillator to describe the bond mode. We predict appreciable changes in energy and small changes in intensity for the high overtone spectrum. The energies and intensities are well described using an effective potential that differs slightly from the original Morse oscillator. © 1979 American Chemical Society.

引用

收藏

页码：1455 / 1457

页数：3

相关论文

共 11 条

[1]

BRAY RM, UNPUBLISHED

[2]

Cross P. C, 1955, MOL VIBRATIONS

[3] NORMAL COORDINATES FOR PLANAR VIBRATIONS OF BENZENE [J].

DUINKER, JC ;

MILLS, IM .

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1968, A 24 (04) :417-&

[4] THEORY OF VIBRATIONAL OVERTONE LINE-SHAPES OF POLYATOMIC-MOLECULES [J].

HELLER, DF ;

MUKAMEL, S .

JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (01) :463-472

[5] OUT-OF-PLANE FORCE CONSTANTS OF BENZENE [J].

OREILLY, EJ .

JOURNAL OF CHEMICAL PHYSICS, 1969, 51 (05) :2206-&

[6] MORSE OSCILLATOR TRANSITION-PROBABILITIES FOR MOLECULAR BOND MODES [J].

SAGE, ML .

CHEMICAL PHYSICS, 1978, 35 (03) :375-380

[7]

SAGE ML, CHEM PHYS LETT

[8] FREE O-H OVERTONE ABSORPTION OF METHANOLS IN VISIBLE REGION BY THERMAL LENSING SPECTROSCOPY [J].

SWOFFORD, RL ;

LONG, ME ;

BURBERRY, MS ;

ALBRECHT, AC .

JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (02) :664-668

[9] C-H VIBRATIONAL-STATES OF C6D5H AND C6F5H IN VISIBLE REGION BY THERMAL LENSING SPECTROSCOPY - TEST OF LOCAL MODE MODEL [J].

SWOFFORD, RL ;

BURBERRY, MS ;

MORRELL, JA ;

ALBRECHT, AC .

JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (11) :5245-5246

[10] C-H VIBRATIONAL-STATES OF BENZENE, NAPHTHALENE, AND ANTHRACENE IN VISIBLE REGION BY THERMAL LENSING SPECTROSCOPY AND LOCAL MODE MODEL [J].

SWOFFORD, RL ;

LONG, ME ;

ALBRECHT, AC .

JOURNAL OF CHEMICAL PHYSICS, 1976, 65 (01) :179-190