OXIDATIVE CLEAVAGE OF TETRAMETHYLAMMONIUM PENTACARBONYL(1-OXYALKYLIDENE)CHROMATE(0) COMPLEXES - FORMATION OF CARBOXYLIC-ACID DERIVATIVES

被引：15

作者：

SODERBERG, BC

BOWDEN, BA

机构：

[1] Department of Chemistry, University of South Alabama, Mobile

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 06期

关键词：

D O I：

10.1021/om00042a041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of tetramethylammonium pentacarbonyl(1-oxyalkylidene)chromate(0) complexes with iodine in the presence of a base and an alcohol afforded carboxylic acid esters in fair to good yield. Substituting an amine or water for the alcohol produced an amide or a carboxylic acid, respectively. The corresponding complexes of molybdenum and tungsten both gave comparable yields of ester product under the same conditions.

引用

页码：2220 / 2223

页数：4

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