ON STANDARD AND REFERENCE STATES COMPATIBLE WITH THE LCVM MODEL

被引：5

作者：

TZOUVARAS, NP

机构：

[1] 11, Psaron St.

来源：

FLUID PHASE EQUILIBRIA | 1994年 / 97卷

关键词：

THEORY; EQUATION OF STATE; MIXING RULES; CUBIC; EMPIRICAL; EXCESS FUNCTIONS; GROUP CONTRIBUTION; VAPOR LIQUID EQUILIBRIA; LCVM MODEL;

D O I：

10.1016/0378-3812(94)85005-4

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A new equation of state/excess Gibbs energy model, LCVM, has been developed. This work provides a theoretical justification for the mixing rule used in the LCVM model for the parameter alpha(= a/bRT, where a and b are cubic equation of state parameters). This is accomplished by determining standard states for pure components in a mixture, as well as a reference pressure, where the excess Gibbs energy expression obtained from the equation of state and the excess Gibbs energy model used give equal values.

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收藏

页码：53 / 60

页数：8

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