ENTHALPY INCREMENT MEASUREMENTS FROM 4.5 TO 318 K FOR BISMUTH(CR) - THERMODYNAMIC PROPERTIES FROM 0 K TO THE MELTING-POINT

被引:13
作者
ARCHER, DG
机构
[1] Chemical Kinetics and Thermodynamics Division, National Institute of Standards and Technology, Gaithersburg
关键词
D O I
10.1021/je00020a064
中图分类号
O414.1 [热力学];
学科分类号
摘要
Enthalpy increments for bismuth(cr) were measured from 4.5 to 318 K with an adiabatic calorimeter. The calorimeter's performance was demonstrated through comparison of measured enthalpy increments for copper and aluminum oxide to literature values. The effect that different temperature scales had on these comparisons for copper at low temperatures was discussed. The new enthalpy increments for bismuth(cr) were combined with previously measured thermodynamic properties for temperatures below 4 K and above 300 K in order to generate the thermodynamic properties of bismuth(cr) from 0 K to the melting point.
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页码:1015 / 1024
页数:10
相关论文
共 44 条
[1]   The heat capacities of bismuth and bismuth trioxide at low temperatures [J].
Anderson, CT .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1930, 52 :2720-2723
[2]   ADIABATIC CALORIMETER FOR USE AT SUPER-AMBIENT TEMPERATURES - HEAT-CAPACITY OF SYNTHETIC SAPPHIRE (ALPHA-AL2O3) FROM 300-K TO 550-K [J].
ANDREWS, JTS ;
NORTON, PA ;
WESTRUM, EF .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1978, 10 (10) :949-958
[3]  
[Anonymous], 1982, J PHYS CHEM REF DATA
[4]  
[Anonymous], 1973, SELECTED VALUES THER
[5]  
ARCHER DG, 1992, J PHYS CHEM REF DATA, V21, P1, DOI 10.1063/1.555913
[6]   THERMODYNAMIC PROPERTIES OF SYNTHETIC SAPPHIRE (ALPHA-AL2O3), STANDARD REFERENCE MATERIAL 720 AND THE EFFECT OF TEMPERATURE-SCALE DIFFERENCES ON THERMODYNAMIC PROPERTIES [J].
ARCHER, DG .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1993, 22 (06) :1441-1453
[7]   SPECIFIC HEATS OF MANGANESE AND BISMUTH AT LIQUID HYDROGEN TEMPERATURES [J].
ARMSTRONG, LD ;
GRAYSONSMITH, H .
CANADIAN JOURNAL OF RESEARCH SECTION A-PHYSICAL SCIENCES, 1949, 27 (02) :9-16
[8]  
BNADAWI WA, 1987, B CHEM SOC JPN, V60, P3765
[9]  
Bronson H. L., 1938, CAN J RES A, V16, P177, DOI 10.1139/cjr38a-018
[10]   The atomic heat of bismuth temperatures [J].
Carpenter, LG ;
Harle, TF .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1932, 136 (829) :243-250