POLYMER-ANCHORED PALLADIUM (II) COMPLEXES AS CATALYSTS FOR THE CONVERSION OF QUADRICYCLANE TO NORBORNADIENE

被引：37

作者：

KING, RB

HANES, RM

机构：

[1] Department of Chemistry, University of Georgia, Athens

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 07期

关键词：

D O I：

10.1021/jo01321a013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of diphenylphosphinated macroreticular polystyrene with (CH3CN)2PdCl2 gives a polymer-supported palladium(II) chloride which is an active catalyst for the conversion of quadricyclane to norbornadiene. However, the activity of this catalyst is less by factors of 2-85 than that of the soluble catalyst [(C6H6)3P]2PdCl2. The new polymer-supported palladium catalyst, like previously reported polymer-supported catalysts for this reaction, loses some of its activity upon repeated recycling. © 1979, American Chemical Society. All rights reserved.

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页码：1092 / 1094

页数：3

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