RAMAN-SPECTRA OF PYRAZINE RESONANT TO THE S2(PI,PI-STAR) STATE AND THE GEOMETRY IN THE EXCITED-STATE

被引:42
作者
SUZUKA, I [1 ]
UDAGAWA, Y [1 ]
ITO, M [1 ]
机构
[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN
关键词
D O I
10.1016/0009-2614(79)80525-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Raman spectra resonant to the S2(π,π*) state of pyrazine vapor consist of fundamentals, overtones and combinations of only two totally symmetric vibrations, ν1 and ν6a. Combining the Raman with the absorption spectra it is experimentally verified that the molecules deformation upon excitation is reflected on the resonance Raman spectra. © 1979.
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页码:333 / 336
页数:4
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