HIGHLY ORIENTED POLYAMIDE THIN-FILMS PREPARED BY VAPOR-DEPOSITION POLYMERIZATION

被引：35

作者：

KUBONO, A ^{[1
]}

OKUI, N ^{[1
]}

TANAKA, K ^{[1
]}

UMEMOTO, S ^{[1
]}

SAKAI, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT ORGAN & POLYMER MAT,MEGURO KU,TOKYO 152,JAPAN

来源：

THIN SOLID FILMS | 1991年 / 199卷 / 02期

关键词：

D O I：

10.1016/0040-6090(91)90021-O

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Vapor deposition polymerization was carried out by supplying sebacoyl dichloride monomer at a regular interval from an external vacuum system, while 1,10-diaminodecane monomer was evaporated at a constant speed throughout the experiment. The alternate reaction of the two monomers epitaxially on the substrate, where the diamine molecule had already been deposited with perpendicular orientation, resulted in the formation of polyamide thin films with almost perfect molecular orientation perpendicular to the substrate.

引用

页码：385 / 393

页数：9

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