SYNTHESIS OF THE 1ST HETEROBIMETALLIC RHENIUM-RUTHENIUM ETA-2-DIHYDROGEN COMPLEXES

被引：19

作者：

CAZANOUE, M

HE, ZL

NEIBECKER, D

MATHIEU, R

机构：

[1] UNIV PAUL SABATIER,CNRS,CHIM COORDINAT LAB,UP 8241,205 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

[2] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 05期

关键词：

D O I：

10.1039/c39910000307

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex [(PPh3)2HRe(mu-H)3(mu-CO)RuH(PPh3)2] 1, resulting from the reaction of [ReH6(PPh3)2]- with [RuHCl(CO)(PPh3)3], reacts with chloroform to give [(PPh3)2HRe(mu-Cl)2(mu-H)(mu-CO)RuH(PPh3)2] 2; protonation of 1 and 2 with HBF4.Et2O leads to the formation of the fluxional [(PPh3)2HRe(mu-H)3(mu-CO)Ru(eta-2-H2)(PPh3)2][BF4]3, and the rigid [(PPh3)2HRe(mu-H)(mu-Cl)2(mu-CO)Ru(eta-2-H2)(PPh3)2] [BF4] 4 complexes.

引用

页码：307 / 309

页数：3

共 17 条

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