CROSS-AXIS SYNCHRONOUS FLOW-THROUGH COIL PLANET CENTRIFUGE (TYPE-XLL) .2. SPECULATION ON THE HYDRODYNAMIC MECHANISM IN STATIONARY PHASE RETENTION

被引：10

作者：

ITO, Y

机构：

[1] Laboratory of Biophysical Chemistry, The National Heart, Lung, Blood Institute, Bethesda, MD 20892, Building 10

来源：

JOURNAL OF CHROMATOGRAPHY | 1991年 / 538卷 / 01期

关键词：

D O I：

10.1016/S0021-9673(01)91622-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The hydrodynamic mechanism involved in the retention of stationary phase in the present x-axis coil planet centrifuge system is discussed. A statistical treatment of the retention data disclosed important clues such as the effect of the inward-outward elution mode, the close correlation between the planetary motion and the head-tail elution mode, and the superior retention capacity of the left-handed coils. The combined effects of the radial and lateral centrifugal force field derived from the mathematical analysis of acceleration acting on the coil provide an explanation for the phenomena.

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页码：67 / 80

页数：14

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