sigma-Bonded Dioxygen. X-Ray Crystal Structure of [NEt4](3)[Co(CN)(5)(O-2)],5H(2)O

被引：19

作者：

Brown, Leo D. ^{[1
]}

Raymond, Kenneth N. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1974年 / 12期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1039/c39740000470

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal and molecular structure of a dioxygen adduct of [Co(CN)(5)](3-) has been determined, the complex is best formulated as a nearly linear superoxide complex of Co-III with a Co-O-O angle of 175 degrees.

引用

页码：470 / 471

页数：2

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