OXOVANADIUM-CATALYZED OXIDATIVE POLYMERIZATION OF DIPHENYL DISULFIDES WITH OXYGEN

被引：62

作者：

YAMAMOTO, K ^{[1
]}

TSUCHIDA, E ^{[1
]}

NISHIDE, H ^{[1
]}

JIKEI, M ^{[1
]}

OYAIZU, K ^{[1
]}

机构：

[1] WASEDA UNIV,DEPT POLYMER CHEM,TOKYO 169,JAPAN

来源：

MACROMOLECULES | 1993年 / 26卷 / 13期

关键词：

D O I：

10.1021/ma00065a029

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Oligo(p-phenylene sulfide) is synthesized through oxygen oxidative polymerization of diphenyl disulfide catalyzed by vanadyl acetylacetonate. The mechanistic studies reveal that two redox cycles [V(M)/V(IV) and V(IV)/V(V)] give rise to catalysis through a 2-electron transfer between diphenyl disulfide and molecular oxygen. The VO catalysts act as an excellent electron mediator to bridge a 1.0-V potential gap between the oxidation potential of disulfides and the reduction potential of oxygen. The VO-catalyzed oxygen oxidative polymerization provides pure oligo(p-phenylene sulfide)s containing an S-S bond. The polymeric product is of low molecular weight due to the insolubility of poly(p-phenylene sulfide) under these experimental conditions.

引用

页码：3432 / 3437

页数：6

共 32 条

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[2]

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[3]

CAPOZZI G, 1974, J CHEM SOC PERK T, V2, P900

[4] THERMODYNAMICS OF COORDINATION TO AN UNSOLVATED POSITION IN VANADYL ACETYLACETONATE [J].