OPTICAL REFLECTANCE SPECTRA OF CR3+ IN MGO SOLID SOLUTIONS

被引：4

作者：

MONTGOMERY, TS

机构：

[1] Ceramic Engineering Department, University of Missouri, Rolla, Missouri

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1969年 / 52卷 / 09期

关键词：

D O I：

10.1111/j.1151-2916.1969.tb09197.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The effect of Cr3+ concentration in an MgO crystal lattice on the crystal field splitting energy, 10 Dq, and on other electronic transitions was studied. Optical reflectance spectra showed a linear increase in 10 Dq with increasing Cr3+ concentration up to the limit of solid solubility. The Racah parameter, B, decreased and the energy of the 4T1g→4A2g transition increased with increasing Cr3+ concentration. The increase in 10 Dq was related to the decrease in lattice parameter. Copyright © 1969, Wiley Blackwell. All rights reserved

引用

页码：478 / +

页数：1

共 18 条

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