STUDIES ON ORGANOLANTHANIDE COMPLEXES .39. SYNTHESIS AND MOLECULAR-STRUCTURE OF (MECP)3LA (MECP = CH3C5H4) - A TETRAMERIC COMPLEX OF THE TYPE [(MECP)3LA]4

被引：27

作者：

XIE, ZW ^{[1
]}

HAHN, FE ^{[1
]}

QIAN, CT ^{[1
]}

机构：

[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,ORGANOMET CHEM LAB,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 414卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)83252-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of LaCl3 with excess Na(MeCp) in THF, followed by sublimation, affords (MeCp)3La. The complex crystallizes as a tetramer [(MeCp)3La]4 in the monoclinic space group P21/c with unit cell dimensions a 9.6785(14), b 26.058(5), c 12.506(2) angstrom, beta-97.724(13)-degrees and Z = 2 (tetramers).

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页码：C12 / C14

页数：3

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