STUDIES ON ORGANOLANTHANIDE COMPLEXES .39. SYNTHESIS AND MOLECULAR-STRUCTURE OF (MECP)3LA (MECP = CH3C5H4) - A TETRAMERIC COMPLEX OF THE TYPE [(MECP)3LA]4

被引:27
作者
XIE, ZW [1 ]
HAHN, FE [1 ]
QIAN, CT [1 ]
机构
[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,ORGANOMET CHEM LAB,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA
关键词
D O I
10.1016/0022-328X(91)83252-Y
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of LaCl3 with excess Na(MeCp) in THF, followed by sublimation, affords (MeCp)3La. The complex crystallizes as a tetramer [(MeCp)3La]4 in the monoclinic space group P21/c with unit cell dimensions a 9.6785(14), b 26.058(5), c 12.506(2) angstrom, beta-97.724(13)-degrees and Z = 2 (tetramers).
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页码:C12 / C14
页数:3
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