STEREOCHEMICAL STUDY OF IMINES AND THEIR N-BORANE ADDUCTS BY H-1-NMR, B-11 NMR, C-13 NMR AND N-15 NMR

被引：19

作者：

ARIZACASTOLO, A ^{[1
]}

PAZSANDOVAL, MA ^{[1
]}

CONTRERAS, R ^{[1
]}

机构：

[1] INST POLITECN NACL, CTR INVEST & ESTUDIOS AVANZADOS, DEPT QUIM, APARTADO POSTAL 14-740, MEXICO CITY 07000, DF, MEXICO

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1992年 / 30卷 / 06期

关键词：

C-13; NMR; H-1; B-11 NMR AND N-15 NMR 1J(C-13; C-13) COUPLING CONSTANTS; CONFIGURATIONAL ASSIGNMENT; NORMAL-BORANE-IMINES;

D O I：

10.1002/mrc.1260300612

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and NMR spectra of the N-borane adducts of two diimines, N-borane-bis(alpha-phenylethylidene)ethylenediamine and N-borane-bis(alpha-phenylbenzylidene)ethylenediamine, and four imines, N-borane-alpha-methylethylidene-2-phenylethylamine, two N-borane-alpha-phenylethylidene-n-butylamines and N-borane-alpha-phenylbenzylidene-n-butylamine, are reported. The NMR spectra of the N-borane adducts of these imines can be used to determine their configuration.

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收藏

页码：520 / 526

页数：7

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