DOUBLE OXIDATIVE ADDITION-REACTIONS OF ALDEHYDES AND KETONES AT TRIOSMIUM CLUSTERS

被引：15

作者：

AZAM, KA

DEEMING, AJ

ROTHWELL, IP

机构：

[1] Department of Chemistry, University College London, London, WC1H OAJ

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 178卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)94237-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclohexanone (C6H10O) reacts with Os3(CO)12 in refluxing decane to give H2Os3(μ3-C6H8O)(CO)9, formed by double metallation (oxidative addition) at an α-CH2 group of the ketone. Structurally similar products from phenol, phenyl-acetaldehyde or other aldehydes (described earlier) and from cyclohexenone are derived by reaction with Os3(CO)12 or H2Os3(CO)10. © 1979.

引用

页码：C20 / C22

页数：3

共 3 条

[1] INTERCONVERSION OF MU2-PHENOLATO AND MU3-OXODIENEDIYL LIGANDS IN TRIOSMIUM CLUSTERS - X-RAY CRYSTAL-STRUCTURE OF 1,1,1,2,2,2,3,3,3-NONACARBONYL-1,2-2,3-DI-MU-HYDRIDO-(MU3-3-BENZYL-2-OXOCYCLOHEXA-3,5-DIENE-1,1-DIYL-1,2-C1-3-O)-TRIANGULO-TRIOSMIUM(3OS-OS) [J].