TIME-OF-FLIGHT STUDY OF H(2S) AND D(2S) PRODUCED BY ELECTRON-IMPACT ON H-2, D-2, AND HD - EVIDENCE FOR PREDISSOCIATION

被引:23
作者
RYAN, SR [1 ]
SPEZESKI, JJ [1 ]
KALMAN, OF [1 ]
LAMB, WE [1 ]
MCINTYRE, LC [1 ]
WING, WH [1 ]
机构
[1] UNIV ARIZONA,DEPT PHYS,TUCSON,AZ 85721
来源
PHYSICAL REVIEW A | 1979年 / 19卷 / 06期
关键词
D O I
10.1103/PhysRevA.19.2192
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Time-of-flight spectra of H(2S) and D(2S) fragments from electron-bombardment-dissociated H2, D2, and HD have been observed. Structure in the kinetic-energy distributions below 1.3 eV is interpreted as arising from predissociation of bound vibrational levels. For H2 and D2 the primary predissociation process appears to be predissociation of the D state via the B′ state. Predissociation structure for HD, although more prominent than for H2 and D2, is not as easily interpreted. Evidence for the direct dissociation of the B′ state has also been obtained and the relative probabilities of direct dissociation and predissociation have been estimated. © 1979 The American Physical Society.
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页码:2192 / 2196
页数:5
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